Discovered on the streets of Budapest at the age of 13, Palvin shot her first editorial in 2006 for Spur Magazine. Palvin subsequently moved to Asia where she maintained a steady stream of bookings. Since then, Palvin has been on the cover of L'Officiel (Paris, Russia, Turkey, Thailand, Singapore), Vogue (Portugal), Marie Claire (Italy, Hungary), Glamour Hungary , Elle (Britain, Italy, Korea, Brazil, Argentina, Sweden, Serbia, Hungary), Allure, Harper's Bazaar and Jealouse Magazine. Palvin has appeared in campaigns for Armani Exchange, H&M, Victoria's Secret, and Pull & Bear. In February 2012, she became an ambassador for L'Oréal Paris. In 2016, Palvin was revealed to be a part of the 2016 Sports Illustrated Swimsuit Rookie Class. She also became the new face of Armani's signature scent "Acqua di Gioia. " Palvin is the face of Amazon Fashion and appeared on Express and Chaos advertising campaigns.