Discovered on the streets of Budapest at the age of 13 by a modeling scout, Palvin shot her first editorial in 2006 for Spur Magazine. Palvin subsequently moved to Asia where she maintained a steady stream of bookings. Since then, Palvin has been on the cover of L'Officiel (Paris, Russia, Turkey, Thailand, Singapore), Vogue (Portugal), Marie Claire (Italy, Hungary), Glamour Hungary, Elle (Britain, Italy, Korea, Brazil, Argentina, Sweden, Serbia, Hungary), Allure, Harper's Bazaar and Jealouse Magazine. Palvin has appeared in campaigns for Armani Exchange, H&M, Victoria's Secret, and Pull & Bear. In February 2012, she became an ambassador for L'Oréal Paris. In 2016, Palvin was revealed to be a part of the Sports Illustrated Swimsuit Rookie Class. She also became the new face of Armani's signature scent "Acqua di Gioia. " Palvin is the face of Amazon Fashion and appeared on Express and Chaos advertising campaigns.